Self-assembly, faster ion transport, high durability, increased retention rate, exquisite specific capacitance are some key characteristics of polyaniline based supercapacitors.
Polyaniline (PANi) as one kind of conducting polymers has been playing a great role in the energy storage and conversion devices besides carbonaceous materials and metallic compounds. Due to high specific capacitance, high flexibility and low cost, PANi has shown great potential in supercapacitor. It alone can be used in fabricating an electrode.
Polyaniline (PANI) as a pseudocapacitive material has very high theoretical capacitance of 2000 F g –1. However, its practical capacitance has been limited by low electrochemical surface area (ESA) and unfavorable wettability toward aqueous electrolytes.
Is modified polyaniline a promising material as a capacitor?
Our experimental results were further supported by first-principles density functional theory calculations and demonstrate that modified polyaniline is a promising material as a capacitor.
Why does polyaniline lose capacitance after 1000 cycles?
PANI tend to degrade and undergoes volumetric instability during repeated charge/discharge cycling which lead to fast decline in the capacitance of polyaniline. Apparently supercapacitor electrode made of pure PANI tend to loose over 50 % of their capacitance after 1000 cycles .
Polyaniline, as conducting polymer, particularly in nano-morphology, has been one of the pioneer electroactive materials paving the corridor for commercial development of pseudocapacitors.
Why is polyaniline a good conductor for energy storage?
They have distinctive features, which includes rapid charging and discharging capabilities, exceptional energy and power densities, and prolonged stability. Polyaniline is one of the most studied conducting polymers for energy storage application because of its high capacity and electrochemical properties but poor cyclability.